Iodometry, also known as iodometric titration, is a method of volumetric chemical analysis, a redox titration where the appearance or disappearance of. Q What is the difference between Iodimetric titrations and Iodometric titrations? Ans. IODIMETRIC TITRATIONS When an analyte that is a reducing agent (like. Iodometry is an indirect titration method whereas iodimetry is a direct titration method. This is the main difference between Iodometry and.

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What is the difference between iodometry and iodimetry? – Quora

Ask New Question Sign In. This tool looks for lower prices at other stores while you shop on Amazon and tells you where to buy. Although the sulfide content in sample can be determined straight forwardly as described for sulfites, the results are often poor and inaccurate.

Related Questions What is the principle of iodimetry? For prolonged titrations, it is advised to add dry ice to the titration mixture to displace air from the erlenmeyer flask so as to prevent the aerial oxidation of iodide to iodine.

The most important thing in this presentation is for you to understand the differences between iodometric and iodimetric titrations. In this method, excess but known amount of iodide is added to known volume of sample, in which only the active electrophilic can oxidize iodide to iodine. What is difference between enantiomers and diasteriomers?

This indicates the end point of the titration. Do you remember other redox titrations that we have done in the laboratory? Standard iodine solutions are of fairly limited use compared to oxidants because of their small electrode potential.


This titrating species is a standard solution of a reducing agent, which is capable of reducing iodine back to iodide form. Introduction to iodometric and iodimetric titrations Example: Available chlorine refers to chlorine liberated by the action of dilute acids on hypochlorite.

And a standard solution of this is used for the iodimetric titrations. Forms of SO 2 in wine Once sulphur dioxide is added to wine it does not remain free but oxidates in part and in part combines with other molecues: As we said before titrations that create or consume I2 are widely used in quantitative analysis.

Here, the Iodine reduces to Iodide ions while the thiosulfate ions get oxidized further. The titration reaction can be represented as:. Both involve iodine, but as you will see there are some differences. With a mind rooted firmly to basic principals of chemistry and passion for ever evolving field of industrial chemistry, she is keenly interested to be a true companion for those who seek knowledge in the subject of chemistry.

Starch can be used as an indicator in iodimetric titrations too. In fact, both these terms refer to different methods of using Iodine in titrations to determine the concentration of an analyte under investigation. Two reactions are involved. Retrieved from ” https: And this is directly titrated with a standard Iodine solution at the presence of titrwtion suitable indicator.

Difference Between Iodometry and Iodimetry

The total sulphur dioxide in the wine sample is determined through direct iodimetric titration using starch iofimetry the indicator. Ascorbic acid Dehydroascorbic acid Pictures taken from: You also know that an analyte is the substance being analyzed.


Iodine forms a deep-blue colour complex with starch and as the Iodine breaks down to Iodide ions, the colour disappears.

Now, we are going to look at the redox titrations involving iodine. Therefore, by determining the end point of the reaction, equations can be derived to obtain information of the stoichiometry and other necessary relationships between the reducing agent and Iodine which acts as the oxidizing agent in this case. With red wines it is difficult to see the equivalence point because their intense red colour makes it difficult titraation perceive the colour change in the indicator.

For example, if we want to quantify the amount of chlorine dissolved in a mixture, the following is the method to carry out an iodometric titration. Published by Juliana Lynch Modified over 3 years ago.

In our case, the analyte is the substance that is being quantified. Iodometry and iodimetry are two common titration methods used in analytical chemistry.

Consequently, in the first reaction The analyte reacts with an excess of iodur to generate iode. The analyte is an oxidizing agent.

Introduction to iodometric and iodimetric titrations In this lesson: Awarded from the Generalitat de Catalunya, Slide 1: It is used because it is necessary to quantify copper in water, alloys, minerals and so on.